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Copper Silicides with the Highest Lithium Content: Li 7 CuSi 2 Containing the 16‐Electron Group [CuSi 2 ] 7− and Li 7.3 CuSi 3 with Heterographene Nets ${{{\hfill 2\atop \hfill \infty }}}$ [CuSi] 3.3−
Author(s) -
Slabon Adam,
Budnyk Serhiy,
CuervoReyes Eduardo,
Wörle Michael,
Mensing Christian,
Nesper Reinhard
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203504
Subject(s) - lithium (medication) , ternary operation , content (measure theory) , group (periodic table) , chemistry , crystal structure , crystallography , inorganic chemistry , computer science , mathematics , organic chemistry , medicine , mathematical analysis , programming language , endocrinology
Incredibly rich in lithium : The ternary silicides Li 7 CuSi 2 with the linear [Si‐Cu‐Si] 7− Zintl anion (see picture) and Li 7.3 CuSi 3 are compounds with the highest lithium content in the ternary system. The crystal and electronic structures of both compounds are discussed.