Copper Silicides with the Highest Lithium Content: Li 7 CuSi 2  Containing the 16‐Electron Group [CuSi 2 ] 7−  and Li 7.3 CuSi 3  with Heterographene Nets  ${{{\hfill 2\atop \hfill \infty }}}$ [CuSi] 3.3− | Zendy

Slabon Adam | Zendy; Budnyk Serhiy | Zendy; CuervoReyes Eduardo | Zendy; Wörle Michael | Zendy; Mensing Christian | Zendy; Nesper Reinhard | Zendy

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Copper Silicides with the Highest Lithium Content: Li 7 CuSi 2 Containing the 16‐Electron Group [CuSi 2 ] 7− and Li 7.3 CuSi 3 with Heterographene Nets ${{{\hfill 2\atop \hfill \infty }}}$ [CuSi] 3.3−

Author(s) -

Slabon Adam,

Budnyk Serhiy,

CuervoReyes Eduardo,

Wörle Michael,

Mensing Christian,

Nesper Reinhard

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203504

Subject(s) - lithium (medication) , ternary operation , content (measure theory) , group (periodic table) , chemistry , crystal structure , crystallography , inorganic chemistry , computer science , mathematics , organic chemistry , medicine , mathematical analysis , programming language , endocrinology

Incredibly rich in lithium : The ternary silicides Li 7 CuSi 2 with the linear [Si‐Cu‐Si] 7− Zintl anion (see picture) and Li 7.3 CuSi 3 are compounds with the highest lithium content in the ternary system. The crystal and electronic structures of both compounds are discussed.

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