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1,3,5‐Benzenetriamine Double‐ and Triple‐Decker Molecules
Author(s) -
Sakamaki Daisuke,
Ito Akihiro,
Tanaka Kazuyoshi,
Furukawa Ko,
Kato Tatsuhisa,
Shiro Motoo
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203451
Subject(s) - information retrieval , library science , physics , crystallography , computer science , chemistry
Double‐ and triple‐decker oligoarylamines have been prepared and characterized by X‐ray crystallography for the first time (see picture; C black, N blue). The N ‐dianisylaminophenyl‐substituted double decker exhibited the multiredox activity, and the oxidized species were confirmed to be in high‐spin states on the basis of pulsed ESR spectroscopy.