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Induced Self‐Assembly of a Tetrathiafulvalene‐Based Open‐Shell Dyad through Intramolecular Electron Transfer
Author(s) -
Guasch Judith,
Grisanti Luca,
Lloveras Vega,
VidalGancedo José,
Souto Manuel,
Morales Dayana C.,
Vilaseca Marta,
Sissa Cristina,
Painelli Anna,
Ratera Imma,
Rovira Concepció,
Veciana Jaume
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203448
Subject(s) - tetrathiafulvalene , intramolecular force , dyad , electron transfer , self assembly , acceptor , materials science , shell (structure) , electron donor , electron , open shell , chemistry , photochemistry , nanotechnology , stereochemistry , molecule , physics , organic chemistry , condensed matter physics , acoustics , composite material , catalysis , quantum mechanics
An organic switch : An open‐shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π‐donor tetrathiafulvalene unit through a vinylene π‐bridge, was synthesized (see picture). The self‐assembly of the dyad in solution induced by its intramolecular electron transfer was studied.