Two Zeolite‐Type Frameworks in One Metal–Organic Framework with Zn 24 @Zn 104  Cube‐in‐Sodalite Architecture | Zendy

Bu Fei | Zendy; Lin Qipu | Zendy; Zhai Quanguo | Zendy; Wang Le | Zendy; Wu Tao | Zendy; Zheng ShouTian | Zendy; Bu Xianhui | Zendy; Feng Pingyun | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Two Zeolite‐Type Frameworks in One Metal–Organic Framework with Zn 24 @Zn 104 Cube‐in‐Sodalite Architecture

Author(s) -

Bu Fei,

Lin Qipu,

Zhai Quanguo,

Wang Le,

Wu Tao,

Zheng ShouTian,

Bu Xianhui,

Feng Pingyun

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203425

Subject(s) - sodalite , monomer , cage , zeolite , zinc , crystallography , cube (algebra) , chemistry , metal , materials science , polymer , organic chemistry , combinatorics , mathematics , catalysis

Two in one : A metal–organic framework obtained from three different inorganic building blocks (tetrameric Zn 4 O, trimeric Zn 3 OH, and monomeric Zn) posseses a nested cage‐in‐cage and framework‐in‐framework architecture (see picture). 24 Zn 4 O tetramers and eight Zn monomers form a sodalite cage into which a cubic cage made from eight Zn 3 (OH) trimers is nestled. Eight monomeric Zn 2+ centers interconnect these two cages.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research