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Two Zeolite‐Type Frameworks in One Metal–Organic Framework with Zn 24 @Zn 104 Cube‐in‐Sodalite Architecture
Author(s) -
Bu Fei,
Lin Qipu,
Zhai Quanguo,
Wang Le,
Wu Tao,
Zheng ShouTian,
Bu Xianhui,
Feng Pingyun
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203425
Subject(s) - sodalite , monomer , cage , zeolite , zinc , crystallography , cube (algebra) , chemistry , metal , materials science , polymer , organic chemistry , combinatorics , mathematics , catalysis
Two in one : A metal–organic framework obtained from three different inorganic building blocks (tetrameric Zn 4 O, trimeric Zn 3 OH, and monomeric Zn) posseses a nested cage‐in‐cage and framework‐in‐framework architecture (see picture). 24 Zn 4 O tetramers and eight Zn monomers form a sodalite cage into which a cubic cage made from eight Zn 3 (OH) trimers is nestled. Eight monomeric Zn 2+ centers interconnect these two cages.