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Binding of Molecular Magnesium Hydrides to a Zirconocene–Enyne Template
Author(s) -
Bender Georg,
Wiegand Thomas,
Eckert Hellmut,
Fröhlich Roland,
Daniliuc Constantin G.,
MückLichtenfeld Christian,
Ndambuki Sylvester,
Ziegler Tom,
Kehr Gerald,
Erker Gerhard
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203372
Subject(s) - enyne , magnesium , hydride , magnesium hydride , olefin fiber , zirconium , chemistry , combinatorial chemistry , inorganic chemistry , organic chemistry , catalysis , metal
An enyne–zirconium complex stabilizes molecular magnesium hydride (MgH 2 ) and even a molecular hydride, n C 4 H 9 MgH. These systems feature magnesium olefin π complexation.