Dizincation of a 2‐Substituted Thiophene: Constructing a Cage with a [16]Crown‐4 Zincocyclic Core | Zendy

Balloch Liam | Zendy; Garden Jennifer A. | Zendy; Kennedy Alan R. | Zendy; Mulvey Robert E. | Zendy; Rantanen Toni | Zendy; Robertson Stuart D. | Zendy; Snieckus Victor | Zendy

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Dizincation of a 2‐Substituted Thiophene: Constructing a Cage with a [16]Crown‐4 Zincocyclic Core

Author(s) -

Balloch Liam,

Garden Jennifer A.,

Kennedy Alan R.,

Mulvey Robert E.,

Rantanen Toni,

Robertson Stuart D.,

Snieckus Victor

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203344

Subject(s) - thiophene , core (optical fiber) , crown (dentistry) , tandem , cage , computer science , chemistry , information retrieval , nanotechnology , materials science , organic chemistry , telecommunications , combinatorics , mathematics , composite material

Metal detector : A bowl‐shaped nanomolecule (see picture; S yellow, C gray, Zn blue) containing an unprecedented 16‐atom [ZnC 3 ] 4 “anti‐crown” ring has been unearthed by isolating a dizincated 2‐substituted thiophene intermediate that would normally be hidden in tandem functionalization methodology.

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