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Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature
Author(s) -
Wang QingLun,
Southerland Heather,
Li JianRong,
Prosvirin Andrey V.,
Zhao Hanhua,
Dunbar Kim R.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203309
Subject(s) - magnet , crystal (programming language) , crystallography , transformation (genetics) , block (permutation group theory) , crystal structure , dehydration , materials science , single crystal , chemistry , physics , geometry , computer science , mathematics , quantum mechanics , biochemistry , gene , programming language
Two for one : Two unusual magnets based on the [Mo(CN) 7 ] 4− building block with Mn II linkers have been prepared with different topological 3D networks. Conversion of one into the other is triggered by dehydration during a single‐crystal to single‐crystal event (see picture; Mn: dark red, Mo: pink, C: green, N: blue, O: red).