Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature | Zendy

Wang QingLun | Zendy; Southerland Heather | Zendy; Li JianRong | Zendy; Prosvirin Andrey V. | Zendy; Zhao Hanhua | Zendy; Dunbar Kim R. | Zendy

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Crystal‐to‐Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature

Author(s) -

Wang QingLun,

Southerland Heather,

Li JianRong,

Prosvirin Andrey V.,

Zhao Hanhua,

Dunbar Kim R.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203309

Subject(s) - magnet , crystal (programming language) , crystallography , transformation (genetics) , block (permutation group theory) , crystal structure , dehydration , materials science , single crystal , chemistry , physics , geometry , computer science , mathematics , quantum mechanics , biochemistry , gene , programming language

Two for one : Two unusual magnets based on the [Mo(CN) 7 ] 4− building block with Mn II linkers have been prepared with different topological 3D networks. Conversion of one into the other is triggered by dehydration during a single‐crystal to single‐crystal event (see picture; Mn: dark red, Mo: pink, C: green, N: blue, O: red).

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