Watching Water Migration around a Peptide Bond | Zendy

Tanabe Kohei | Zendy; Miyazaki Mitsuhiko | Zendy; Schmies Matthias | Zendy; Patzer Alexander | Zendy; Schütz Markus | Zendy; Sekiya Hiroshi | Zendy; Sakai Makoto | Zendy; Dopfer Otto | Zendy; Fujii Masaaki | Zendy

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Watching Water Migration around a Peptide Bond

Author(s) -

Tanabe Kohei,

Miyazaki Mitsuhiko,

Schmies Matthias,

Patzer Alexander,

Schütz Markus,

Sekiya Hiroshi,

Sakai Makoto,

Dopfer Otto,

Fujii Masaaki

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203296

Subject(s) - acetanilide , ligand (biochemistry) , peptide , photoionization , peptide bond , bond , chemistry , linkage (software) , computer science , crystallography , business , ion , organic chemistry , biochemistry , receptor , ionization , finance , gene

A long and winding road : The motion of a single water ligand around a peptide bond in acetanilide was probed in real time by time‐resolved IR spectroscopy. Triggered by photoionization, the H 2 O ligand is released from the CO site of the peptide linkage and trapped after a migration time of 5 ps at the NH site of the same peptide bond (see picture).

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