Cyclic Distiba‐ and Dibismadiazenium Cations | Zendy

Lehmann Mathias | Zendy; Schulz Axel | Zendy; Villinger Alexander | Zendy

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Cyclic Distiba‐ and Dibismadiazenium Cations

Author(s) -

Lehmann Mathias,

Schulz Axel,

Villinger Alexander

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203267

Subject(s) - trifluoromethanesulfonate , halide , abstraction , chemistry , terphenyl , content (measure theory) , medicinal chemistry , information retrieval , stereochemistry , computer science , philosophy , organic chemistry , mathematics , epistemology , catalysis , mathematical analysis

Think positive, keep the anions away : Hitherto unknown mono‐ and dications of the type [XE(μ‐NTerE)] + and [E 2 (μ‐NTer) 2 ] 2+ (E=Sb, Bi; X=Cl, I) were studied and fully characterized for the first time. Salts bearing these highly reactive cations can be obtained from terphenyl‐substituted cyclo ‐dipnictadiazanes [XE(μ‐NR)] 2 by halide abstraction or triflate substitution.

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