CH Activation in S‐Alkenyl Sulfoximines: An Endo 1,5‐Hydrogen Migration | Zendy

Gao Xuefeng | Zendy; Gaddam Vikram | Zendy; Altenhofer Erich | Zendy; Tata Rama Rao | Zendy; Cai Zhengxin | Zendy; Yongpruksa Nattawut | Zendy; Garimallaprabhakaran Aswin K. | Zendy; Harmata Michael | Zendy

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CH Activation in S‐Alkenyl Sulfoximines: An Endo 1,5‐Hydrogen Migration

Author(s) -

Gao Xuefeng,

Gaddam Vikram,

Altenhofer Erich,

Tata Rama Rao,

Cai Zhengxin,

Yongpruksa Nattawut,

Garimallaprabhakaran Aswin K.,

Harmata Michael

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203258

Subject(s) - intramolecular force , hydride , chemistry , alkyl , redox , medicinal chemistry , class (philosophy) , combinatorial chemistry , hydrogen , stereochemistry , organic chemistry , computer science , artificial intelligence

Intramolecular redox reaction : Heating N‐alkyl, N‐allyl‐, and N‐benzyl‐substituted S‐alkenyl sulfoximines under appropriate conditions results in the formation of NH‐S‐alkyl sulfoximines. The intramolecular redox reaction involves a hydride transfer that occurs by a 6‐ endo ‐trig process. The intermediates in the reaction can also give access to four‐ and six‐membered heterocyclic rings and a new class of chiral dienes.

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