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Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group
Author(s) -
Wang Chengming,
Chen Hu,
Wang Zhaofeng,
Chen Jiean,
Huang Yong
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203230
Subject(s) - triazene , rhodium , surface modification , catalysis , chemistry , group (periodic table) , combinatorial chemistry , organic chemistry
Diverse opportunities : A Rhodium(III)‐catalyzed ortho ‐selective olefination of arenes using a novel triazene as a directing group is reported. This method exhibits substantial post‐functionalization synthetic versatility, overcoming a vital limitation in C sp 2H activation/functionalization products: restricted structural diversity.
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