Continuous‐Flow Hydrogenation of Carbon Dioxide to Pure Formic Acid using an Integrated scCO 2  Process with Immobilized Catalyst and Base | Zendy

Wesselbaum Sebastian | Zendy; Hintermair Ulrich | Zendy; Leitner Walter | Zendy

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Continuous‐Flow Hydrogenation of Carbon Dioxide to Pure Formic Acid using an Integrated scCO 2 Process with Immobilized Catalyst and Base

Author(s) -

Wesselbaum Sebastian,

Hintermair Ulrich,

Leitner Walter

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203185

Subject(s) - formic acid , catalysis , supercritical carbon dioxide , supercritical fluid , ruthenium , ionic liquid , materials science , base (topology) , carbon dioxide , chemical engineering , inorganic chemistry , chemistry , organic chemistry , mathematical analysis , mathematics , engineering

Dual role for CO 2 : Pure formic acid can be obtained continuously by hydrogenation of CO 2 in a single processing unit (see scheme). An immobilized ruthenium organometallic catalyst and a nonvolatile base in an ionic liquid (IL) are combined with supercritical CO 2 as both reactant and extractive phase.

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