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Inside Back Cover: Rational Construction of an Extrinsic Porous Molecular Crystal with an Extraordinary High Specific Surface Area (Angew. Chem. Int. Ed. 21/2012)
Author(s) -
Mastalerz Michael,
Oppel Iris M.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203156
Subject(s) - cover (algebra) , porosity , materials science , molecule , hydrogen bond , crystal (programming language) , porous medium , solvent , chemical engineering , crystallography , organic molecules , nanotechnology , chemistry , organic chemistry , composite material , computer science , programming language , mechanical engineering , engineering
Porous molecular crystals are accessible by the directed self‐assembly of a molecular organic precursor by hydrogen bonding. As M. Mastalerz and I. M. Oppel describe in their Communication on page 5252 ff., enclosed solvent molecules were removed from the pores, leading to a permanently porous material with a specific surface area of 2796 m 2 g −1 . The material adsorbs CO 2 selectively over CH 4 , and also adsorbs relatively high amounts of H 2 .