Bis[ N , N ′‐diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand | Zendy

Junold Konstantin | Zendy; Baus Johannes A. | Zendy; Burschka Christian | Zendy; Tacke Reinhold | Zendy

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Bis[ N , N ′‐diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand

Author(s) -

Junold Konstantin,

Baus Johannes A.,

Burschka Christian,

Tacke Reinhold

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203109

Subject(s) - denticity , silicon , silylene , ligand (biochemistry) , chemistry , stereochemistry , medicinal chemistry , computer science , crystallography , organic chemistry , crystal structure , receptor , biochemistry

Well looked‐after : Reductive HCl elimination of the λ 6 ‐silicon(IV) complex 1 leads to the λ 3 ‐silicon(II) species 2 , a novel type of donor‐stabilized silylene. Reaction of 2 with [W(CO) 6 ] and with I 2 yields the λ 5 ‐silicon(II) complex 3 and the λ 6 ‐silicon(IV) complex 4 , respectively.

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