Premium
Bis[ N , N ′‐diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand
Author(s) -
Junold Konstantin,
Baus Johannes A.,
Burschka Christian,
Tacke Reinhold
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203109
Subject(s) - denticity , silicon , silylene , ligand (biochemistry) , chemistry , stereochemistry , medicinal chemistry , computer science , crystallography , organic chemistry , crystal structure , receptor , biochemistry
Well looked‐after : Reductive HCl elimination of the λ 6 ‐silicon(IV) complex 1 leads to the λ 3 ‐silicon(II) species 2 , a novel type of donor‐stabilized silylene. Reaction of 2 with [W(CO) 6 ] and with I 2 yields the λ 5 ‐silicon(II) complex 3 and the λ 6 ‐silicon(IV) complex 4 , respectively.