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The Role of Co‐Adsorbed CO and OH in the Electrooxidation of Formic Acid on Pt(111)
Author(s) -
Gao Wang,
Mueller Jonathan E.,
Jiang Qing,
Jacob Timo
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203078
Subject(s) - formic acid , adsorption , chemistry , density functional theory , kinetic energy , computational chemistry , inorganic chemistry , organic chemistry , physics , quantum mechanics
Synergy with potential : Analysis of relevant mechanistic pathways by density functional theory, reveals the synergistic role of co‐adsorbed CO and OH in promoting HCOOH electrooxidation on Pt(111). Kinetic models derived from these studies show the atomistic surface phenomena underlying the experimental CV observation in the potential range between 0.0 and 1.2 V (see picture).