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An Ionothermal Synthetic Approach to Porous Polyoxometalate‐Based Metal–Organic Frameworks
Author(s) -
Fu Hai,
Qin Chao,
Lu Ying,
Zhang ZhiMing,
Li YangGuang,
Su ZhongMin,
Li WenLiang,
Wang EnBo
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202994
Subject(s) - porosity , polyoxometalate , adsorption , porous medium , ion exchange , metal organic framework , process (computing) , materials science , chemical engineering , metal , transition metal , nanotechnology , inorganic chemistry , chemistry , ion , computer science , organic chemistry , catalysis , metallurgy , engineering , operating system
Pretty porous POMs : Ionothermal synthesis was applied to prepare porous POM‐based open frameworks. The structural integrity remains unchanged until 300 °C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition‐metal ions through a cation‐exchange process, and subsequent gas adsorption measurements confirm their permanent porosity.