An Ionothermal Synthetic Approach to Porous Polyoxometalate‐Based Metal–Organic Frameworks | Zendy

Fu Hai | Zendy; Qin Chao | Zendy; Lu Ying | Zendy; Zhang ZhiMing | Zendy; Li YangGuang | Zendy; Su ZhongMin | Zendy; Li WenLiang | Zendy; Wang EnBo | Zendy

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An Ionothermal Synthetic Approach to Porous Polyoxometalate‐Based Metal–Organic Frameworks

Author(s) -

Fu Hai,

Qin Chao,

Lu Ying,

Zhang ZhiMing,

Li YangGuang,

Su ZhongMin,

Li WenLiang,

Wang EnBo

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202994

Subject(s) - porosity , polyoxometalate , adsorption , porous medium , ion exchange , metal organic framework , process (computing) , materials science , chemical engineering , metal , transition metal , nanotechnology , inorganic chemistry , chemistry , ion , computer science , organic chemistry , catalysis , metallurgy , engineering , operating system

Pretty porous POMs : Ionothermal synthesis was applied to prepare porous POM‐based open frameworks. The structural integrity remains unchanged until 300 °C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition‐metal ions through a cation‐exchange process, and subsequent gas adsorption measurements confirm their permanent porosity.

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