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Structure and Reactivity of an Iodosylarene Adduct of a Manganese(IV)–Salen Complex
Author(s) -
Wang Chunlan,
Kurahashi Takuya,
Fujii Hiroshi
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202835
Subject(s) - manganese , adduct , reactivity (psychology) , chemistry , crystal structure , ligand (biochemistry) , substrate (aquarium) , crystallography , polymer chemistry , organic chemistry , medicine , biochemistry , oceanography , alternative medicine , receptor , pathology , geology
O transfer : The X‐ray crystal structure of an iodosylarene adduct of a manganese(IV)–salen complex shows bis‐iodosylarene coordination with a stepped conformation of the salen ligand. Spectroscopic characterization suggests that the complex maintains the same structure in solution. A reactivity study indicates that the manganese‐bound iodosylarene can directly transfer an oxygen atom to substrate.