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An Organotransition‐Metal Complex with Pentagonal‐Pyramidal Structure
Author(s) -
GarcíaMonforte M. Angeles,
Baya Miguel,
Falvello Larry R.,
Martín Antonio,
Menjón Babil
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202819
Subject(s) - pentagonal bipyramidal molecular geometry , metal , materials science , crystallography , chemistry , crystal structure , metallurgy
Star gazing : The six‐coordinate organoniobium( V ) compound [NBu 4 ] 2 [NbO(C 6 F 5 ) 5 ] has been found to exhibit a pentagonal‐pyramidal ( PPY ‐6) structure, which is unprecedented in organotransition‐metal chemistry (see picture: complex as viewed down the O–Nb axis; C in gray, O in red, F in yellow, and Nb in blue).