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Inside Cover: Photoswitchable Dynamic Magnetic Relaxation in a Well‐Isolated {Fe 2 Co} Double‐Zigzag Chain (Angew. Chem. Int. Ed. 21/2012)
Author(s) -
Dong DaPeng,
Liu Tao,
Kanegawa Shinji,
Kang Soonchul,
Sato Osamu,
He Cheng,
Duan ChunYing
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202782
Subject(s) - zigzag , antiferromagnetism , chain (unit) , relaxation (psychology) , crystallography , int , materials science , irradiation , cover (algebra) , chemistry , condensed matter physics , physics , mechanical engineering , psychology , social psychology , geometry , mathematics , computer science , engineering , operating system , astronomy , nuclear physics
A cooperative, reversible charge‐transfer‐induced spin transition that occurs upon cooling and heating of the well‐isolated cyanide‐bridged Fe III 2 Co II double‐zigzag chain {[Fe(pzTp)(CN) 3 ] 2 Co(4‐styrylpyridine) 2 }⋅2H 2 O⋅2CH 3 OH (pzTp=tetrakis(pyrazolyl)borate) is described in the Communication by T. Liu, O. Sato, C.‐Y. Duan et al. on page 5119 ff. Irradiation of the chain with 532 nm light at 5 K results in a single‐chain magnetic behavior with no antiferromagnetic ordering after the irradiation.
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