Fullerene Doping: Preparation of Azafullerene C 59 NH and Oxafulleroids C 59 O 3  and C 60 O 4 | Zendy

Xin Nana | Zendy; Huang Huan | Zendy; Zhang Jianxin | Zendy; Dai Zhifei | Zendy; Gan Liangbing | Zendy

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Fullerene Doping: Preparation of Azafullerene C 59 NH and Oxafulleroids C 59 O 3 and C 60 O 4

Author(s) -

Xin Nana,

Huang Huan,

Zhang Jianxin,

Dai Zhifei,

Gan Liangbing

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202777

Subject(s) - fullerene , oxygen , carbon fibers , doping , nitrogen , oxygen atom , chemistry , content (measure theory) , materials science , organic chemistry , molecule , optoelectronics , mathematics , composite number , composite material , mathematical analysis

Breaking the surface : Replacement of a fullerene cage carbon with a nitrogen or oxygen atom is achieved by reactions mediated with fullerene peroxide. Similar procedures have also generated oxafulleroids with oxygen atoms inserted into the cage skeleton. The dioxafullerene C 58 O 2 was selectively generated in the gas phase under MALDI‐TOF conditions.

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