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Fullerene Doping: Preparation of Azafullerene C 59 NH and Oxafulleroids C 59 O 3 and C 60 O 4
Author(s) -
Xin Nana,
Huang Huan,
Zhang Jianxin,
Dai Zhifei,
Gan Liangbing
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202777
Subject(s) - fullerene , oxygen , carbon fibers , doping , nitrogen , oxygen atom , chemistry , content (measure theory) , materials science , organic chemistry , molecule , optoelectronics , mathematics , composite number , composite material , mathematical analysis
Breaking the surface : Replacement of a fullerene cage carbon with a nitrogen or oxygen atom is achieved by reactions mediated with fullerene peroxide. Similar procedures have also generated oxafulleroids with oxygen atoms inserted into the cage skeleton. The dioxafullerene C 58 O 2 was selectively generated in the gas phase under MALDI‐TOF conditions.