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Borylene Transfer from an Iron Bis(borylene) Complex: Synthesis of 1,4‐Diboracyclohexadiene and 1,4‐Dibora‐1,3‐Butadiene Complexes
Author(s) -
Braunschweig Holger,
Ye Qing,
Radacki Krzysztof,
Damme Alexander
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202764
Subject(s) - chemistry , scheme (mathematics) , stereochemistry , combinatorial chemistry , computer science , information retrieval , mathematics , mathematical analysis
Diene to be made : By tuning the size of acetylenic substituents, 1,4‐diboracyclohexadiene and unprecedented 1,4‐dibora‐1,3‐butadiene complexes were generated in a controlled manner by borylene transfer from an iron bis(borylene) complex to alkynes (see scheme).