An Iron(III) Iodosylbenzene Complex: A Masked Non‐Heme Fe V O | Zendy

Lennartson Anders | Zendy; McKenzie Christine J. | Zendy

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An Iron(III) Iodosylbenzene Complex: A Masked Non‐Heme Fe V O

Author(s) -

Lennartson Anders,

McKenzie Christine J.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202487

Subject(s) - oxidizing agent , ligand (biochemistry) , combinatorial chemistry , chemistry , flexibility (engineering) , heme , metal , sulfide , catalysis , computer science , organic chemistry , biochemistry , receptor , statistics , mathematics , enzyme

Coordinative flexibility and ligand bifunctionality play important roles in a biomimetic iron complex of a hexadentate ligand (see picture). This system can bind an auxiliary iodosylbenzene ligand to give the first structurally characterized metal complex of this important oxidizing agent. The complex is a protected precursor for Fe V O species, and the selective high‐yielding catalytic oxygenation of a sulfide is demonstrated.

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