Asymmetric Synthesis and Biosynthetic Implications of (+)‐Fusarisetin A | Zendy

Yin Jun | Zendy; Wang Cheng | Zendy; Kong Lili | Zendy; Cai Shujun | Zendy; Gao Shuanhu | Zendy

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Asymmetric Synthesis and Biosynthetic Implications of (+)‐Fusarisetin A

Author(s) -

Yin Jun,

Wang Cheng,

Kong Lili,

Cai Shujun,

Gao Shuanhu

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202455

Subject(s) - intramolecular force , computer science , transformation (genetics) , content (measure theory) , information retrieval , chemistry , combinatorial chemistry , stereochemistry , biochemistry , mathematics , gene , mathematical analysis

Starting from equisetin , the asymmetric synthesis of (+)‐fusarisetin A has been accomplished in a one‐pot transformation including a biomimetic oxidation and an intramolecular Diels–Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.

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