Premium
Isolation of the Magic‐Size CdSe Nanoclusters [(CdSe) 13 ( n ‐octylamine) 13 ] and [(CdSe) 13 (oleylamine) 13 ]
Author(s) -
Wang Yuanyuan,
Liu YiHsin,
Zhang Ying,
Wang Fudong,
Kowalski Paul J.,
Rohrs Henry W.,
Loomis Richard A.,
Gross Michael L.,
Buhro William E.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202380
Subject(s) - oleylamine , nanoclusters , magic (telescope) , materials science , crystallography , chemistry , nanotechnology , nanocrystal , physics , quantum mechanics
Pure magic : CdSe nanoclusters with a magic size have previously been obtained only as mixtures. Two ligated forms of (CdSe) 13 have now been isolated by exfoliation of nanocluster– n ‐octylamine bilayer aggregates followed by release of [(CdSe) 13 ( n ‐octylamine) 13 ] or freely soluble [(CdSe) 13 (oleylamine) 13 ] nanoclusters by ligand exchange.