Separation of Enantiomers and CD Spectra of Au 40 (SCH 2 CH 2 Ph) 24 : Spectroscopic Evidence for Intrinsic Chirality | Zendy

Knoppe Stefan | Zendy; Dolamic Igor | Zendy; Dass Amala | Zendy; Bürgi Thomas | Zendy

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Separation of Enantiomers and CD Spectra of Au 40 (SCH 2 CH 2 Ph) 24 : Spectroscopic Evidence for Intrinsic Chirality

Author(s) -

Knoppe Stefan,

Dolamic Igor,

Dass Amala,

Bürgi Thomas

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202369

Subject(s) - chirality (physics) , enantiomer , spectral line , cluster (spacecraft) , chemistry , crystallography , stereochemistry , analytical chemistry (journal) , materials science , physics , chiral symmetry , chromatography , quantum mechanics , computer science , nambu–jona lasinio model , programming language , quark

Chirality unveiled : Thiolate‐protected Au 40 (SR) 24 clusters were enantioenriched using an HPLC approach. CD spectra show strong mirror‐image responses, indicating the intrinsic chirality of a cluster of unknown structure protected with achiral ligands.

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