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Stepwise Construction of the CrCr Quintuple Bond and Its Destruction upon Axial Coordination
Author(s) -
Huang YuLun,
Lu DuanYen,
Yu HsienCheng,
Yu JenShiang K.,
Hsu ChiaWei,
Kuo TingShen,
Lee GeneHsiang,
Wang Yu,
Tsai YiChou
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202337
Subject(s) - chemistry , chromium , bond , crystallography , organic chemistry , business , finance
Give me five! Terdentate 2,6‐diamidopyridyl ligands were used to stabilize the CrCr quintuple bond and have made it possible to isolate and characterize not only the CrCr quintuple‐bonded complex, but also the mixed‐valent intermediates (Cr I and Cr II ), which are important species in the formation of type I quintuple‐bonded complexes.