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An Alkaline Earth I 3 O 0 Porous Coordination Polymer: [Ba 2 TMA(NO 3 )(DMF)]
Author(s) -
Foo Maw Lin,
Horike Satoshi,
Inubushi Yasutaka,
Kitagawa Susumu
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202285
Subject(s) - barium , alkaline earth metal , polymer , trimesic acid , thermal stability , coordination polymer , molecular sieve , strontium , methane , oxygen , chemistry , inorganic chemistry , materials science , alkali metal , molecule , organic chemistry , catalysis
A CO 2 sieve : [Ba 2 TMA(NO 3 )(DMF)] (DMF=dimethylformamide, H 3 TMA=trimesic acid) is a main group, porous I 3 O 0 coordination polymer that is connected in all three dimensions with barium‐oxygen‐barium bonds, leading to good thermal stability. The one‐dimensional channels of this framework are decorated with protruding oxygen atoms and can separate carbon dioxide from methane under kinetic breakthrough conditions at 273 K.