Interfacial Self‐Assembly of Water‐Soluble Cationic Porphyrins for the Reduction of Oxygen to Water | Zendy

Olaya Astrid J. | Zendy; Schaming Delphine | Zendy; Brevet PierreFrancois | Zendy; Nagatani Hirohisa | Zendy; Xu HaiJun | Zendy; Meyer Michel | Zendy; Girault Hubert H. | Zendy

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Interfacial Self‐Assembly of Water‐Soluble Cationic Porphyrins for the Reduction of Oxygen to Water

Author(s) -

Olaya Astrid J.,

Schaming Delphine,

Brevet PierreFrancois,

Nagatani Hirohisa,

Xu HaiJun,

Meyer Michel,

Girault Hubert H.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202266

Subject(s) - cationic polymerization , chemistry , oxygen , self assembly , water soluble , inorganic chemistry , organic chemistry

Meet at the border : Assembly of the water‐soluble cobalt tetrakis( N ‐methylpyridinium‐4‐yl)porphyrin [CoTMPyP] 4+ at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C 6 F 5 ) 4 B − . The supramolecular structure thus formed (see picture) provides excellent catalytic activity in the four‐electron reduction of oxygen.

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