A Light‐Induced Phase Exhibiting Slow Magnetic Relaxation in a Cyanide‐Bridged [Fe 4 Co 2 ] Complex | Zendy

Nihei Masayuki | Zendy; Okamoto Yuki | Zendy; Sekine Yoshihiro | Zendy; Hoshino Norihisa | Zendy; Shiga Takuya | Zendy; Liu Isiah PoChun | Zendy; Oshio Hiroki | Zendy

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A Light‐Induced Phase Exhibiting Slow Magnetic Relaxation in a Cyanide‐Bridged [Fe 4 Co 2 ] Complex

Author(s) -

Nihei Masayuki,

Okamoto Yuki,

Sekine Yoshihiro,

Hoshino Norihisa,

Shiga Takuya,

Liu Isiah PoChun,

Oshio Hiroki

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202225

Subject(s) - metastability , cyanide , relaxation (psychology) , phase (matter) , magnetic relaxation , magnetic susceptibility , condensed matter physics , magnet , materials science , phase transition , molecule , chemistry , nuclear magnetic resonance , chemical physics , crystallography , magnetic field , physics , magnetization , inorganic chemistry , psychology , social psychology , organic chemistry , quantum mechanics

Single‐molecule magnets : A cyanide‐bridged hexanuclear complex showed a thermal electron‐transfer‐coupled spin transition centered at 220 K. Light irradiation at low temperature (LT; HT=high temperature) generated a metastable state showing slow magnetic relaxation in measurements of the alternating‐current magnetic susceptibility ( χ m ; see picture).

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