Hydrogen Activation by an Intramolecular Boron Lewis Acid/Zirconocene Pair | Zendy

Podiyanachari Santhosh Kumar | Zendy; Fröhlich Roland | Zendy; Daniliuc Constantin G. | Zendy; Petersen Jeffrey L. | Zendy; MückLichtenfeld Christian | Zendy; Kehr Gerald | Zendy; Erker Gerhard | Zendy

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Hydrogen Activation by an Intramolecular Boron Lewis Acid/Zirconocene Pair

Author(s) -

Podiyanachari Santhosh Kumar,

Fröhlich Roland,

Daniliuc Constantin G.,

Petersen Jeffrey L.,

MückLichtenfeld Christian,

Kehr Gerald,

Erker Gerhard

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202218

Subject(s) - zirconium , borane , intramolecular force , lewis acids and bases , boron , frustrated lewis pair , alkyne , chemistry , hydrogen , content (measure theory) , medicinal chemistry , stereochemistry , catalysis , organic chemistry , mathematics , mathematical analysis

Let's split : Reaction of the zirconium complex A with Piers' borane [HB(C 6 F 5 ) 2 ] yields the unusual borylalkyne zirconocene complex B which reacts with dihydrogen, activating it to give the doubly hydrido bridged alkyne zirconium complex C .

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