Isolation and Characterization of Stable Iron(I) Sulfide Complexes | Zendy

Rodriguez Meghan M. | Zendy; Stubbert Bryan D. | Zendy; Scarborough Christopher C. | Zendy; Brennessel William W. | Zendy; Bill Eckhard | Zendy; Holland Patrick L. | Zendy

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Isolation and Characterization of Stable Iron(I) Sulfide Complexes

Author(s) -

Rodriguez Meghan M.,

Stubbert Bryan D.,

Scarborough Christopher C.,

Brennessel William W.,

Bill Eckhard,

Holland Patrick L.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202211

Subject(s) - sulfide , oxidation state , characterization (materials science) , chemistry , metal , alkali metal , iron sulfide , inorganic chemistry , combinatorial chemistry , sulfur , nanotechnology , materials science , organic chemistry

The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well‐known in synthetic and biological systems. Spectroscopic and computational studies show a high‐spin d 7 configuration at the metal. Alkali metal cations play a key role in supporting the unusually low oxidation state.

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