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High‐Nuclearity Silver Ethynide Clusters Assembled with Phosphonate and Metavanadate Precursors
Author(s) -
Xie YunPeng,
Mak Thomas C. W.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201202195
Subject(s) - synthon , phosphonate , chemistry , cluster (spacecraft) , template , supramolecular chemistry , polymer chemistry , chloride , metal , crystallography , inorganic chemistry , stereochemistry , organic chemistry , nanotechnology , materials science , crystal structure , computer science , programming language
Giant mixed‐metal clusters have been assembled with the multinuclear silver(I) tert ‐butylethynide supramolecular synthon and phosphonate‐functionalized oxovanadate building blocks as surface components. Various anionic species can be used as their encapsulated templates. (Picture: Ag 36 cluster anion encapsulating a chloride (sphere) and two [(O 2 )(V 2 O 6 )] 4− template anions (dark green); Ag blue, O red, P yellow, V green).