Integrative Self‐Sorting Synthesis of a Fe 8 Pt 6 L 24  Cubic Cage | Zendy

Smulders Maarten M. J. | Zendy; Jiménez Azucena | Zendy; Nitschke Jonathan R. | Zendy

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Integrative Self‐Sorting Synthesis of a Fe 8 Pt 6 L 24 Cubic Cage

Author(s) -

Smulders Maarten M. J.,

Jiménez Azucena,

Nitschke Jonathan R.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201202050

Subject(s) - cage , tetrahedron , cube (algebra) , sorting , crystallography , ion , computer science , combinatorics , chemistry , nanotechnology , materials science , algorithm , mathematics , organic chemistry

96 bonds were formed when 62 building blocks (heterotopic ligands with Fe II and Pt II ions) self‐assembled in a one‐pot reaction into a heterometallic Fe 8 Pt 6 L 24 cubic cage (see model, Fe purple, Pt orange, N blue). The dynamic nature of this method also allowed an efficient cage‐to‐cage conversion: a tetrahedral Fe 4 L 6 cage was converted into the Fe 8 Pt 6 L 24 cube, which was subsequently converted into a second tetrahedral Fe 4 L′ 6 cage.

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