Development of an O 2 ‐Sensitive Fluorescence‐Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation | Zendy

Gerken James B. | Zendy; Chen Jamie Y. C. | Zendy; Massé Robert C. | Zendy; Powell Adam B. | Zendy; Stahl Shan S. | Zendy

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Development of an O 2 ‐Sensitive Fluorescence‐Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation

Author(s) -

Gerken James B.,

Chen Jamie Y. C.,

Massé Robert C.,

Powell Adam B.,

Stahl Shan S.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201201999

Subject(s) - oxide , quenching (fluorescence) , metal , catalysis , fluorescence , combinatorial chemistry , chemistry , nanotechnology , rare earth , inorganic chemistry , computer science , materials science , physics , mineralogy , organic chemistry , quantum mechanics

Realizing their potential : The title assay has enabled rapid screening of diverse mixed‐metal oxide electrocatalysts composed exclusively of earth‐abundant metal ions. Several newly discovered catalyst compositions (e.g., Ni/Al/Fe oxides) exhibit substantially lower overpotentials for water oxidation than known, widely used electrocatalysts.

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