Premium
Low‐Temperature Isolation of An Azidophosphenium Cation
Author(s) -
Hering Christian,
Schulz Axel,
Villinger Alexander
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201851
Subject(s) - chemistry , salt (chemistry) , ion , characterization (materials science) , planar , crystallography , inorganic chemistry , materials science , nanotechnology , organic chemistry , computer graphics (images) , computer science
Trapped in the cold : The synthesis and structural characterization of a GaCl 4 − salt bearing an azidophosphenium cation is presented for the first time. This formal phosphapentacenium ion with a planar molecular skeleton is only stable at temperatures below −30 °C.