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Oxidative CarbonCarbon Bond Cleavage of a α‐Hydroxy Ketone by a Functional Model of 2,4′‐Dihydroxyacetophenone Dioxygenase
Author(s) -
Paria Sayantan,
Halder Partha,
Paine Tapan Kanti
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201825
Subject(s) - dioxygenase , ketone , chemistry , cleavage (geology) , bond cleavage , carbon fibers , ligand (biochemistry) , carbon chain , stereochemistry , oxidative cleavage , catalysis , organic chemistry , enzyme , biochemistry , computer science , biology , fracture (geology) , composite number , paleontology , receptor , algorithm
Bond cleavage : An iron(II)–α‐hydroxy ketone complex of a facial tridentate nitrogen donor ligand undergoes a CC bond cleavage reaction in the presence of dioxygen to form two equivalents of carboxylic acids. This reaction is a functional model of 2,4′‐dihydroxyacetophenone dioxygenase.