Oxidative CarbonCarbon Bond Cleavage of a α‐Hydroxy Ketone by a Functional Model of 2,4′‐Dihydroxyacetophenone Dioxygenase | Zendy

Paria Sayantan | Zendy; Halder Partha | Zendy; Paine Tapan Kanti | Zendy

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Oxidative CarbonCarbon Bond Cleavage of a α‐Hydroxy Ketone by a Functional Model of 2,4′‐Dihydroxyacetophenone Dioxygenase

Author(s) -

Paria Sayantan,

Halder Partha,

Paine Tapan Kanti

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201201825

Subject(s) - dioxygenase , ketone , chemistry , cleavage (geology) , bond cleavage , carbon fibers , ligand (biochemistry) , carbon chain , stereochemistry , oxidative cleavage , catalysis , organic chemistry , enzyme , biochemistry , computer science , biology , fracture (geology) , composite number , paleontology , receptor , algorithm

Bond cleavage : An iron(II)–α‐hydroxy ketone complex of a facial tridentate nitrogen donor ligand undergoes a CC bond cleavage reaction in the presence of dioxygen to form two equivalents of carboxylic acids. This reaction is a functional model of 2,4′‐dihydroxyacetophenone dioxygenase.

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