Premium
Dihydrogen‐Catalyzed Reversible Carbon–Hydrogen and Nitrogen–Hydrogen Bond Formation in Organometallic Iridium Complexes
Author(s) -
Valpuesta José E. V.,
Rendón Nuria,
LópezSerrano Joaquín,
Poveda Manuel L.,
Sánchez Luis,
Álvarez Eleuterio,
Carmona Ernesto
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201811
Subject(s) - iridium , isomerization , catalysis , chemistry , hydrogen , nitrogen , cleavage (geology) , carbon fibers , medicinal chemistry , photochemistry , organic chemistry , materials science , composite number , fracture (geology) , composite material
Dihydrogen at work! H 2 catalyzes with high efficiency a prototropic rearrangement of aminopyridinate ligands bound to a {(η 5 ‐C 5 Me 5 )Ir III } unit. The catalytic isomerization implies reversible formation and cleavage of HH, CH, and NH bonds.