Ribbons, Vesicles, and Baskets: Supramolecular Assembly of a Coil–Plate–Coil Emeraldicene Derivative | Zendy

Wang Mingfeng | Zendy; Mohebbi Ali Reza | Zendy; Sun Yanming | Zendy; Wudl Fred | Zendy

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Ribbons, Vesicles, and Baskets: Supramolecular Assembly of a Coil–Plate–Coil Emeraldicene Derivative

Author(s) -

Wang Mingfeng,

Mohebbi Ali Reza,

Sun Yanming,

Wudl Fred

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201201796

Subject(s) - vesicle , supramolecular chemistry , materials science , nanotechnology , self assembly , conjugated system , derivative (finance) , tetrahydrofuran , nano , molecule , nanometre , crystallography , chemistry , composite material , polymer , membrane , organic chemistry , biochemistry , solvent , financial economics , economics

Concentration matters : The self‐assembly of title compound 1 evolves from well‐defined ribbons to vesicles to baskets (see picture), upon simply decreasing the concentration of 1 in tetrahydrofuran. Electron microscopy revealed a unique self‐assembled structure: baskets are formed by curved and self‐wrapped nanometer‐thin ribbons. The self‐assembly of π‐conjugated molecule 1 enables to construct nano/micro structures with desired optoelectronic properties.

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