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Thermal Reactions of YAlO 3 +. with Methane: Increasing the Reactivity of Y 2 O 3 +. and the Selectivity of Al 2 O 3 +. by Doping
Author(s) -
Ma JiaBi,
Wang ZheChen,
Schlangen Maria,
He ShengGui,
Schwarz Helmut
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201698
Subject(s) - heteronuclear molecule , reactivity (psychology) , methane , selectivity , hydrogen , chemistry , oxide , analytical chemistry (journal) , inorganic chemistry , stereochemistry , catalysis , nuclear magnetic resonance spectroscopy , organic chemistry , medicine , alternative medicine , pathology
HAT in hand : The heteronuclear oxide cluster YAlO 3 +. exhibits higher reactivity and selectivity than Y 2 O 3 +. and Al 2 O 3 +. , respectively, in the reaction with methane by hydrogen‐atom transfer (HAT) at room temperature (see scheme).