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Multiple‐Charged P 1 ‐Centered Cations: Perspectives in Synthesis
Author(s) -
Feldmann KaiOliver,
Weigand Jan J.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201600
Subject(s) - homogeneous , reagent , catalysis , homogeneous catalysis , transition metal , chemistry , center (category theory) , phosphorus , combinatorial chemistry , nanotechnology , organic chemistry , materials science , crystallography , physics , thermodynamics
Taking center stage : Several new features of the title compounds were recently uncovered. P 1 ‐centered cations are employed as reagents for the preparation of unprecedented phosphorus compounds and transition‐metal complexes. This represents a remarkable extension of their chemistry, which might make an impact on the field of homogeneous catalysis.