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Inside Cover: Sequential, Kinetically Controlled Synthesis of Multicomponent Stereoisomeric Assemblies (Angew. Chem. Int. Ed. 17/2012)
Author(s) -
Chepelin Oleg,
Ujma Jakub,
Barran Perdita E.,
Lusby Paul J.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201577
Subject(s) - int , cover (algebra) , trigonal crystal system , sequence (biology) , chemistry , platinum , stereochemistry , combinatorial chemistry , crystallography , nanotechnology , catalysis , materials science , computer science , organic chemistry , crystal structure , biochemistry , engineering , mechanical engineering , operating system
A kinetically controlled approach to metallosupramolecular assembly has been demonstrated by P. J. Lusby and co‐workers in their Communication on page 4194 ff. By exploiting asymmetric cyclometalated platinum corner units that possess both labile and nonlabile cis ‐coordination sites, trigonal prismatic stereoisomeric architectures have been selectively prepared by altering the sequence of addition of molecular structural components using a template‐free method.