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Reversible Electron Transfer in a Linear {Fe 2 Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion
Author(s) -
Liu Tao,
Dong DaPeng,
Kanegawa Shinji,
Kang Soonchul,
Sato Osamu,
Shiota Yoshihito,
Yoshizawa Kazunari,
Hayami Shinya,
Wu Shuo,
He Cheng,
Duan ChunYing
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201201305
Subject(s) - electron transfer , electron , thermal , chemistry , materials science , thermal treatment , crystallography , thermodynamics , physics , nuclear physics , composite material
A light change : A linear cyanido‐bridged Fe 2 Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar–nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light.