Topochemical Click Reaction: Spontaneous Self‐Stitching of a Monosaccharide to Linear Oligomers through Lattice‐Controlled Azide–Alkyne Cycloaddition | Zendy

Pathigoolla Atchutarao | Zendy; Gonnade Rajesh G. | Zendy; Sureshan Kana M. | Zendy

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Topochemical Click Reaction: Spontaneous Self‐Stitching of a Monosaccharide to Linear Oligomers through Lattice‐Controlled Azide–Alkyne Cycloaddition

Author(s) -

Pathigoolla Atchutarao,

Gonnade Rajesh G.,

Sureshan Kana M.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201201023

Subject(s) - cycloaddition , azide , click chemistry , image stitching , alkyne , chemistry , linear polymer , solvent , polymer chemistry , monosaccharide , polymer , photochemistry , combinatorial chemistry , catalysis , organic chemistry , computer science , artificial intelligence

No activation needed : A topochemical click reaction that dispenses with catalyst, solvent, or other modes of activation takes place in crystals of a sugar derivative. The spontaneous, regiospecific azide–alkyne cycloaddition gives linear polymers that are difficult to synthesize by conventional solution‐state chemistry (see picture).

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