The Reaction of a High‐Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide | Zendy

Braymer Joseph J. | Zendy; O'Neill Kevin P. | Zendy; Rohde JanUwe | Zendy; Lim Mi Hee | Zendy

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The Reaction of a High‐Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide

Author(s) -

Braymer Joseph J.,

O'Neill Kevin P.,

Rohde JanUwe,

Lim Mi Hee

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200901

Subject(s) - hydrogen peroxide , chemistry , reactive oxygen species , heme , perspective (graphical) , peroxide , combinatorial chemistry , photochemistry , organic chemistry , biochemistry , computer science , enzyme , artificial intelligence

An Fe IV O group meets with H 2 O 2 ! Reaction of high‐valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2 O 2 ) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2 O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high‐valent oxometal complexes.

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