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Anodic Oxidation on a Boron‐Doped Diamond Electrode Mediated by Methoxy Radicals
Author(s) -
Sumi Takenori,
Saitoh Tsuyoshi,
Natsui Keisuke,
Yamamoto Takashi,
Atobe Mahito,
Einaga Yasuaki,
Nishiyama Shigeru
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200878
Subject(s) - diamond , radical , anodic oxidation , boron , electrode , anode , chemistry , doping , electrochemistry , inorganic chemistry , photochemistry , materials science , organic chemistry , optoelectronics
Direct evidence : The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron‐doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarin A, was accomplished by the BDD‐mediated anodic oxidation protocol (see picture).