Anodic Oxidation on a Boron‐Doped Diamond Electrode Mediated by Methoxy Radicals | Zendy

Sumi Takenori | Zendy; Saitoh Tsuyoshi | Zendy; Natsui Keisuke | Zendy; Yamamoto Takashi | Zendy; Atobe Mahito | Zendy; Einaga Yasuaki | Zendy; Nishiyama Shigeru | Zendy

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Anodic Oxidation on a Boron‐Doped Diamond Electrode Mediated by Methoxy Radicals

Author(s) -

Sumi Takenori,

Saitoh Tsuyoshi,

Natsui Keisuke,

Yamamoto Takashi,

Atobe Mahito,

Einaga Yasuaki,

Nishiyama Shigeru

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200878

Subject(s) - diamond , radical , anodic oxidation , boron , electrode , anode , chemistry , doping , electrochemistry , inorganic chemistry , photochemistry , materials science , organic chemistry , optoelectronics

Direct evidence : The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron‐doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarin A, was accomplished by the BDD‐mediated anodic oxidation protocol (see picture).

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