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Gold– and Platinum–Bismuth Donor–Acceptor Interactions Supported by an Ambiphilic PBiP Pincer Ligand
Author(s) -
Tschersich Carolin,
Limberg Christian,
Roggan Stefan,
Herwig Christian,
Ernsting Nikolaus,
Kovalenko Sergey,
Mebs Stefan
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200848
Subject(s) - bismuth , pincer movement , platinum , ligand (biochemistry) , acceptor , chemistry , computer science , nanotechnology , materials science , physics , organic chemistry , catalysis , biochemistry , receptor , condensed matter physics
Noble metals meet a heavyweight : A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal→bismuth contributions.