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A Cationic Calcium Hydride Cluster Stabilized by Cyclen‐Derived Macrocyclic N,N,N,N Ligands
Author(s) -
Jochmann Phillip,
Davin Julien P.,
Spaniol Thomas P.,
Maron Laurent,
Okuda Jun
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200690
Subject(s) - hydrosilylation , hydride , cationic polymerization , chemistry , cyclen , catalysis , cluster (spacecraft) , combinatorial chemistry , stereochemistry , organic chemistry , computer science , hydrogen , programming language
Cationic calcium hydride complexes with a [Ca 3 (μ 3 ‐H) 2 ] core were prepared from different organocalcium precursors and Ph 2 SiH 2 . The hydride complexes were found to be active in the catalytic hydrosilylation and hydrogenation of 1,1‐diphenylethene.