Reactivity of Atmospherically Relevant Small Radicals at the Air–Water Interface | Zendy

MartinsCosta Marilia T. C. | Zendy; Anglada Josep M. | Zendy; Francisco Joseph S. | Zendy; RuizLopez Manuel F. | Zendy

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Reactivity of Atmospherically Relevant Small Radicals at the Air–Water Interface

Author(s) -

MartinsCosta Marilia T. C.,

Anglada Josep M.,

Francisco Joseph S.,

RuizLopez Manuel F.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200656

Subject(s) - radical , reactivity (psychology) , aerosol , gas phase , environmental chemistry , chemistry , atmospheric chemistry , redox , chemical physics , environmental science , photochemistry , inorganic chemistry , organic chemistry , ozone , medicine , alternative medicine , pathology

A fish out of water : The chemical properties at the air–water interface of the atmospherically important free radicals HO 2 . and O 2 .− were investigated by means of computer simulations. Acidity, HOMO–LUMO gap, and redox potentials differ from both the bulk and also the gas phase. These findings are significant for HO 2 . chemistry and aerosol and cloud chemistry.

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