Premium
Facile Bucky‐Bowl Synthesis by Regiospecific Cove‐Region Closure by HF Elimination
Author(s) -
Amsharov K. Yu.,
Kabdulov M. A.,
Jansen Martin
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200516
Subject(s) - chemoselectivity , aryl , intramolecular force , closure (psychology) , computer science , process (computing) , power (physics) , combinatorial chemistry , key (lock) , chemistry , organic chemistry , catalysis , political science , programming language , computer security , law , physics , alkyl , quantum mechanics
Building bowls : An effective intramolecular aryl–aryl coupling is the key step in rational fullerene synthesis and in synthesis of extended buckybowl structures. Such a process can be embodied very efficiently through quantitative HF elimination on active Al 2 O 3 . The process is characterized by an unprecedentedly high chemoselectivity and regiospecificity.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom