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Facile Bucky‐Bowl Synthesis by Regiospecific Cove‐Region Closure by HF Elimination
Author(s) -
Amsharov K. Yu.,
Kabdulov M. A.,
Jansen Martin
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200516
Subject(s) - chemoselectivity , aryl , intramolecular force , closure (psychology) , computer science , process (computing) , power (physics) , combinatorial chemistry , key (lock) , chemistry , organic chemistry , catalysis , political science , programming language , computer security , law , physics , alkyl , quantum mechanics
Building bowls : An effective intramolecular aryl–aryl coupling is the key step in rational fullerene synthesis and in synthesis of extended buckybowl structures. Such a process can be embodied very efficiently through quantitative HF elimination on active Al 2 O 3 . The process is characterized by an unprecedentedly high chemoselectivity and regiospecificity.