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O 2 Insertion into a Cadmium–Carbon Bond: Structural Characterization of Organocadmium Peroxides
Author(s) -
Johnson Andrew L.,
Hollingsworth Nathan,
KociokKöhn Gabriele,
Molloy Kieran C.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200448
Subject(s) - cadmium , chemistry , characterization (materials science) , nanotechnology , organic chemistry , materials science
Cadmium burning : The violent reaction of CdMe 2 with O 2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O 2 insertion into the CdC bond, are thus formed (see picture; Cd green, C gray, N blue, O red).
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